Acta Mechanica Slovaca 2017, 21(3):6-11 | DOI: 10.21496/ams.2017.020

Biosorbent from Biowastes for Heavy Metals Removal from Industrial Effluents

József Paulovics1,*, Ljudmilla Bokányi2
1 EMK North Hungarian Environmental Protection Ltd., HU-3792 Sajóbábony, Gyártelep
2 University of Miskolc; HU-3515 Miskolc-Egyetemváros

Biosorption has been considered as a potential technology to remove dissolved toxic heavy metals from industrial effluents including machinery manufacturing effluents. The objectives of the present study were to investigate the adsorption behavior of natural and chemically modified sunflower seed hulls (SF) and soybean hulls (SB) for Pb2+ and Cd2+ in mono-cationic systems. Base washing and citric acid (CA) modification were applied to enhance the adsorption capacity of these biowastes. The adsorption ability is sensitive to pH value in the solution, thus the pH was adjusted to 5...5.2. SF and SB are promising, inexpensive and effective medium for capturing dissolved Pb2+ and Cd2+ from industrial effluents. Moreover citric acid (CA) modification can increase their adsorption capacity. But this effect cannot be recognized in case of our experiments. The mechanism of biosorption was revealed using FT-IR and zeta-potential measurements.

Keywords: Biosorption, heavy metals, sunflower, soybean, lead, cadmium

Published: October 31, 2017  Show citation

ACS AIP APA ASA Harvard Chicago Chicago Notes IEEE ISO690 MLA NLM Turabian Vancouver
Paulovics, J., & Bokányi, L. (2017). Biosorbent from Biowastes for Heavy Metals Removal from Industrial Effluents. Acta Mechanica Slovaca21(3), 6-11. doi: 10.21496/ams.2017.020
Download citation

References

  1. Dhankhar, R., Hooda, A. (2011). Fungal biosorption - an alternative to meet the challenges of heavy metal pollution in aqueous solutions, Environ. Technol., 32, 467-491. Go to original source...
  2. Gadd, G.M. (2009). Biosorption: critical review of scientific rationale, environmental importance and significance for pollution treatment. J. Chem. Technol. Biotechnol., 84, 13-28. Go to original source...
  3. Witek-Krowiak, A. (2012). Analysis of temperature-dependent biosorption of Cu2+ ions on sunflower hulls: Kinetics, equilibrium and mechanism of the process. Chemical Engineering Journal 192, p. 13-20. Go to original source...
  4. Mohammed, A. A. (2015). Biosorption of Lead, Cadmium, and Zinc onto Sunflower Shell: Equilibrium, Kinetic, and Thermodynamic Studies, Iraqi Journal of Chemical and Petroleum Engineering Vol.16 No.1, 91- 105. ISSN: 1997-4884 Go to original source...
  5. Blanes, P., Bordoni, E., González, J., García, S., Atria, A., Sala, L., Bellú, S. (2016). Application of soy hull biomass in removal of Cr(VI) from contaminated waters. Kinetic, thermodynamic and continuous sorption studies, Journal of Environmental Chemical Engineering 4, 516-526. Go to original source...
  6. Kishor, P., Vilas, P., Patil, N., Vijay, M. (2012). Adsorption of Copper (Cu2+) & Zinc (Zn2+) Metal Ion from Waste Water by Using Soybean Hulls and Sugarcane Bagasse as Adsorbent. International Journal of Scientific Research and Reviews, 1(2), 13-23. ISSN: 2279-0543
  7. Li, J., Chen, E., Su H., Tan T. (2011). Biosorption of Pb2+ with Modified Soybean Hulls as Absorbent. Chinese Journal of Chemical Engineering, 19(2) 334-339 Go to original source...
  8. Zhu B., Fan, T., Zhang, D. (2007). Adsorption of copper ions from aqueous solution by citric acid modified soybean straw. Journal of Hazardous Materials 153 (2008) 300-308 Go to original source...
  9. Paulovics, J., Sebe, E., Siska, O., Bokányi, L. (2016). Comparison of biosorption of lead and cadmium on sunflower seed hulls, soybean hulls by-products and algae. Biotechnology & Metals: 4th International Scientific Conference (e-Proceedings), 70-77, ISBN: 978-80-89883-01-1.
  10. Siska, O. (2017) BSc thesis (Supervisors: Dr. L. Bokányi and J. Paulovics. University of Miskolc.
  11. Sebe, E. (2017) BSc thesis (Supervisors: Dr. L. Bokányi and J. Paulovics). University of Miskolc.

This is an open access article distributed under the terms of the Creative Commons Attribution 4.0 International License (CC BY 4.0), which permits use, distribution, and reproduction in any medium, provided the original publication is properly cited. No use, distribution or reproduction is permitted which does not comply with these terms.